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Table 6.
Fitting parameters according to equivalent circuits of Figure 12 after samples exposure to 50 mM NaCl solution.
| 3 h into NaCl | AA-coat-CeMo-MBT | AA-coat-CeMo | AA-coat-MBT | AA-coat |
| CPEcoat − T (nF cm−2 s−n) | 3.4128 | 9.0690 | 3.6800 | 6.9100 |
| CPEcoat − P | 0.94024 | 0.88459 | 0.97177 | 0.94386 |
| Rcoat (kohm cm2) | 97.623 | 31.710 | 60.892 | 46.843 |
| Ccoat (nF cm−2) | 2.0516 | 3.1300 | 2.8828 | 4.2826 |
| CPEint − T (μF cm−2 s−n) | 4.0208 | 6.9589 | 9.8000 | 1.9800 |
| CPEintP | 0.71774 | 0.65745 | 0.95738 | 0.55544 |
| Rint (Mohm cm2) | 8.5694 | 0.34756 | 1.3419 | 1.8251 |
| Cint (μF cm−2) | 0.16176 | 0.11025 | 0.10990 | 5.5114 |
| 24 h into NaCl | AA-coat-CeMo-MBT | AA-coat-CeMo | AA-coat-MBT | AA-coat |
| CPEcoat − T (nF cm−2 s−n) | 4.7636 | 0.26265 | 0.48344 | 0.14507 |
| CPEcoat − P | 0.93143 | 0.80725 | 0.76822 | 0.88811 |
| Rcoat (kohm cm2) | 59.790 | 1.9570 | 1.0600 | 8.8890 |
| Ccoat (nF cm−2) | 2.6117 | 2.4847 | 2.4541 | 4.6940 |
| CPEint − T (μF cm−2 s−n) | 0.54295 | 0.29730 | 0.57929 | 0.45755 |
| CPEintP | 0.64777 | 0.57259 | 0.55692 | 0.56104 |
| Rint (Mohm cm2) | 2.6436 | 0.066245 | 0.030872 | 1.1259 |
| Cint (mF cm−2) | 0.80839 | 0.049307 | 0.091992 | 0.99969 |
| CPEdl − T (mF cm−2 s−n) | – | 1.0120 | 2.2271 | – |
| CPEdl − P | – | 0.99999 | 0.9999 | – |
| Rct (kohm cm2) | – | 41.461 | 31.094 | – |
| Cdl (mF cm−2) | – | 1.0120 | 2.2280 | – |
| 48 h into NaCl | AA-coat-CeMo-MBT | AA-coat-CeMo | AA-coat-MBT | AA-coat |
| CPEcoat − T (nF cm−2 s−n) | 4.0533 | 0.50940 | 0.012000 | 0.32561 |
| CPEcoat − P | 0.93394 | 0.75932 | 0.69918 | 0.82541 |
| Rcoat (kohm cm2) | 50.534 | 1.2800 | 0.78360 | 4.6150 |
| Ccoat (nF cm−2) | 2.2228 | 2.4006 | 2.2218 | 5.0586 |
| CPEint − T (μF cm−2 s−n) | 6.9124 | 0.51703 | 0.78832 | 6.8279 |
| CPEintP | 0.61836 | 0.62059 | 0.65918 | 0.54666 |
| Rint (Mohm cm2) | 1.6518 | 0.024524 | 0.012042 | 0.028375 |
| Cint (μF cm−2) | 31.071 | 59.780 | 76.739 | 1.7506 |
| CPEdl − T (mF cm−2 s−n) | – | 1.2923 | 2.3582 | – |
| CPEdl − P | – | 0.98868 | 0.89822 | – |
| Rct (kohm cm2) | – | 64.287 | 15.565 | – |
| Cdl (mF cm−2) | – | 1.3594 | 3.5472 | – |
| 72 h into NaCl | AA-coat-CeMo-MBT | AA-coat-CeMo | AA-coat-MBT | AA-coat |
| CPEcoat − T (nF cm−2 s−n) | 5.5467 | 102.84 | 123.79 | 148.13 |
| CPEcoat − P | 0.91268 | 0.70594 | 0.69786 | 0.83736 |
| Rcoat (kohm cm2) | 22.170 | 1.2050 | 0.73520 | 0.15590 |
| Ccoat (nF cm−2) | 2.3438 | 2.4253 | 2.2038 | 18.625 |
| CPEint − T (μF cm−2 s−n) | 9.9000 | 62.992 | 88.516 | 42.858 |
| CPEintP | 0.59232 | 0.62325 | 0.67453 | 0.66214 |
| Rint (Mohm cm2) | 1.0742 | 0.025491 | 0.011164 | 0.022073 |
| Cint (μF cm−2) | 50.385 | 83.871 | 88.010 | 41.661 |
| CPEdl − T (mF cm−2 s−n) | – | 1.1985 | 2.4206 | 1.0863 |
| CPEdl − P | – | 0.92355 | 0.98279 | 0.81336 |
| Rct (kohm cm2) | – | 43.501 | 28.240 | 22.233 |
| Cdl (mF cm−2) | – | 1.6626 | 6.3819 | 1.1486 |
| 96 h into NaCl | AA-coat-CeMo-MBT | AA-coat-CeMo | AA-coat-MBT | AA-coat |
| CPEcoat − T (nF cm−2 s−n) | 7.6594 | 118.21 | 127.89 | 5828.8 |
| CPEcoat − P | 0.89169 | 0.69735 | 0.69704 | 0.52896 |
| Rcoat (kohm cm2) | 10.822 | 1.1280 | 0.72430 | 0.29300 |
| Ccoat (nF cm−2) | 2.4459 | 2.4597 | 2.2586 | 20.002 |
| CPEint − T (μF cm−2 s−n) | 13.016 | 65.205 | 82.424 | 45.052 |
| CPEintP | 0.62559 | 0.62498 | 0.69838 | 0.68892 |
| Rint (kohm cm2) | 531.86 | 27.712 | 10.879 | 12.451 |
| Cint (μF cm−2) | 41.436 | 92.996 | 78.632 | 34.701 |
| CPEdl − T (mF cm−2 s−n) | – | 1.8979 | 3.0575 | 0.34636 |
| CPEdl − P | – | 0.99999 | 0.88484 | 0.5744 |
| Rct (kohm cm2) | – | 27.586 | 11.077 | 99.314 |
| Cdl (mF cm−2) | – | 1.8980 | 4.8358 | 4.7645 |
| 193 h into NaCl | AA-coat-CeMo-MBT | AA-coat-CeMo | AA-coat-MBT | AA-coat |
| CPEcoat − T (μF cm−2 s−n) | 0.025382 | 0.13455 | 0.18012 | 2.2289 |
| CPEcoat − P | 0.8133 | 0.70058 | 0.68596 | 0.51252 |
| Rcoat (kohm cm2) | 2.3380 | 0.86620 | 0.64620 | 0.17200 |
| Ccoat (nF cm−2) | 2.7181 | 2.8038 | 2.8477 | 21.274 |
| CPEint − T (μF cm−2 s−n) | 27.931 | 66.688 | 84.408 | 25.929 |
| CPEintP | 0.66931 | 0.65909 | 0.76406 | 0.64324 |
| Rint (kohm cm2) | 92.018 | 27.272 | 10.385 | 77.011 |
| Cint (μF cm−2) | 44.528 | 90.868 | 81.043 | 38.051 |
| CPEdl − T (mF cm−2 s−n) | 1.5802 | 2.2602 | 2.6671 | 2.4590 |
| CPEdl − P | 0.99999 | 0.99999 | 0.88678 | 0.96860 |
| Rct (kohm cm2) | 50.672 | 25.505 | 6.7010 | 39.209 |
| Cdl (mF cm−2) | 1.5803 | 2.2603 | 3.8540 | 2.8450 |
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